| Reactions | | Reaction ID | Precursor | Product | Enzyme | Reaction Type | Data Source | Reference |
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| MMDBr0017422 | (3E,5S)-3-[(2E,4E,8S,10E,12Z)-1-hydroxy-4,8-dimethyltetradeca-2,4,10,12-tetraen-1-ylidene]-5-[(4-hydroxyphenyl)methyl]pyrrolidine-2,4-dione | 3-[(2E,4E,8S,10E,12Z)-4,8-dimethyltetradeca-2,4,10,12-tetraenoyl]-4-hydroxy-5-(4-hydroxyphenyl)-1,2-dihydropyridin-2-one | Cytochrome P450 monooxygenase iccC | Oxygenation | RHEA | 34755880 | | MMDBr0017423 | (3E,5S)-3-[(2E,4E,8S,10E,12Z)-1-hydroxy-4,8-dimethyltetradeca-2,4,10,12-tetraen-1-ylidene]-5-[(4-hydroxyphenyl)methyl]pyrrolidine-2,4-dione | 3-[(2E,4E,8S,10E,12Z)-4,8-dimethyltetradeca-2,4,10,12-tetraenoyl]-4-hydroxy-5-(4-hydroxyphenyl)-1,2-dihydropyridin-2-one | Cytochrome P450 monooxygenase iccC | Oxygenation | RHEA | 34755880 | | MMDBr0017424 | 3-[(2E,4E,8S,10E,12Z)-4,8-dimethyltetradeca-2,4,10,12-tetraenoyl]-4-hydroxy-5-(4-hydroxyphenyl)-1,2-dihydropyridin-2-one | 8-epi-ilicicolin H | S-adenosyl-L-methionine-dependent Diels-Alderase iccD | Diels–Alder reaction | RHEA | 34755880 | | MMDBr0017425 | 3-[(2E,4E,8S,10E,12Z)-4,8-dimethyltetradeca-2,4,10,12-tetraenoyl]-4-hydroxy-5-(4-hydroxyphenyl)-1,2-dihydropyridin-2-one | 8-epi-ilicicolin H | S-adenosyl-L-methionine-dependent Diels-Alderase iccD | Diels–Alder reaction | RHEA | 34755880 | | MMDBr0017426 | 8-epi-ilicicolin H | Ilicicolin H | NADH-dependent flavin oxidoreductase iccE | Redox reaction | RHEA | 34755880 | | MMDBr0017427 | 8-epi-ilicicolin H | Ilicicolin H | NADH-dependent flavin oxidoreductase iccE | Redox reaction | RHEA | 34755880 | | MMDBr0025868 | Malonyl-CoA | S-Adenosylhomocysteine | Hybrid PKS-NRPS synthetase iccA | Synthesis | RHEA | 34755880 | | MMDBr0025869 | Malonyl-CoA | S-Adenosylhomocysteine | Hybrid PKS-NRPS synthetase iccA | Synthesis | RHEA | 34755880 |
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